- 외부 전장이 폴리비닐리덴플루오라이드 결정화 거동에 미치는 영향
- ㆍ 저자명
- 김갑진,이종순
- ㆍ 간행물명
- 韓國纖維工學會誌
- ㆍ 권/호정보
- 2002년|39권 3호|pp.251-258 (8 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The effect of electric field strength upon the rate of overall crystallization, crystal morphology, and crystal modifications was investigated by studying the melt-crystallization of poly(vinylidene fluoride) in the presence of an external dc electric field of 0~0.09 MV/cm. With increase in the exectric field strength. the temperature at which tar electro-active polar ${gamma}$-crystal begins to form decreased and the ${gamma}$-crystal content increased with reduction in the content of the electro-inactive $alpha$-crystal. The transition of $alpha$-crystal to ${gamma}$-crystal was found to be suppressed by the electric field in the course of the isothermal melt-crystallization. The electric field did not have a significant effect on the rate of overall crystallization at 150~ 154 $^{circ}C$ where only $alpha$-crystal was formed. However, the rate of crystallization was reduced by the electric field at slightly higher temperatures (ca. 156-158$^{circ}C$) where a mixture of $alpha$- and ${gamma}$-crystals was formed, whereas the electric field increased the rate of crystallization at 160-162 $^{circ}C$ where ${gamma}$-crystal was preferentially formed.