A diesel engine has various merits such as high thermal-efficiency, superior fuel consumption and durability. Therefore the number of diesel engine in the world is increasing. As the seriousness of environmental pollution increases in the world, the method to reduce the noxious materials of CO2, NOx and P.M. is very important subject to correspond to exhaust gas regulations. A new concept, so called premixed charge compression ignition(PCCI), is focused among the various corresponding manners. In this study, we investigated the combustion characteristics of PCCI engine using a mixed fuels with that of commercial diesel engine. Finally we grasped a emission characteristics of PCCI engine. From this experiment, it could be found that NOx reduction is caused by the lower maximum temperature and soot reduction is caused by rapid combustion under diffusion combustion part. Also, it was found that 1st-combustion(cool flame) and 2nd-combustion(hot flame) is appeared in heat release curve, exhaust gas temperature is diminished and combustion variation is increased according to increasing of gasoline ratio.