In the stereolithography process, the accuracy of product depends on laser power, scan speed, scan width, scan pattern, layer thickness, resin characteristics and so on. Therefore, appropriate process parameters are required for an accurate prototype. This paper presents a method to determine the key process parameters, i.e., laser scan speed, hatching space, and layer thickness based on scan length, scan area, and layer slope. In order to determine these parameters, three neural networks are employed to represent operator’s experience and knowledge. Optimum values on scan speed, hatching space and layer thickness are recommended to improve the surface roughness and build time on the developed SLA machine.