The structures and properties of Cu nanowires have been investigated using molecular dynamics simulations. Cylindrical multi-shell Cu nanowires maintain their structures at room temperature and their structural properties are different from the structural properties of nanowires with face-centered-cubic structure. The results from nanopillar and tensile testing of cylindrical multi-shell Cu nanowire showed structures related to pentagonal needle-like crystal structures. Since the subunits of pentagonal nanowire with needle-like crystal are face-centered-cubic structure, pentagonal multi-shell nanowires are stable one-dimensional structures in nanostructured materials.