cis,cis,trans-[MoBr2(CO)2(PPh3)2］와 2,6-dimethylphenyl isocyanide의 반응으로부터 화합물cis,fac-[Mo(O)Br2,(CN-C6H3,-2,6-Me2)sub 3/] (1)이 분리되었다. 화합물 1의 구조가 분광학적 방법(1H-NMR, 13C｛1H｝-NMR, IR) 및 X-ray 회절법으로 규명되었다. 화합물 1의 결정학 자료: 삼사정계 공 간군 P(equation omitted), a=9.172(2) (equation omitted), b ＝ 11.550(3) (equation omitted), c ＝ 15.106(3) (equation omitted), α ＝ 100.44(2)°, β＝ 107.12(2)°, γ＝ 107.83(1)°, Z ＝ 2, R(wR2) ＝ 0.0529(0.1344).
From the reaction of cis,cis,trans- [MoBr2(CO)2(PPh3)2］with 2,6-dimethylphenyl isocyanide, a molybdenum oxohaloisocyanide compound cis,fac-[Mo(O)Br2,(CN-C6H3,-2,6-Me2)sub 3/] (1) was iso-lated. Compound 1 was characterized by spectroscopy (1H-NMR, 13C｛1H｝-NMR, IR) and X-ray diffraction. Crystallographic data for 1: triclinic space group P(equation omitted), a=9.172(2) (equation omitted), b ＝ 11.550(3) (equation omitted), c ＝ 15.106(3) (equation omitted), α ＝ 100.44(2)°, β＝ 107.12(2)°, γ＝ 107.83(1)°, Z ＝ 2, R(wR2) ＝ 0.0529(0.1344).
