A three-dimensional photochemical air pollution model considered advection, dispersion, photochemical reactions, and precipitation processes was developed. The calculated results of meteorological observation clearly exhibited geographical effects of Gwangyang Bay, in which land and sea breezes, mount-valley winds and local circular winds occurred. The observed results of daytime NOx concentrations were slightly higher than the calculated NOx concentrations in Yosu industrial complex, Gwangyang iron mill, and container yard. Eventually, the calculated NOx results generally agreed well with the observed ones.