Nanocomposite means that the size of the second particles dispersed in the matrix is nanometer order. It was reported that this nanocompostie shows particular properties, different from a general composite in which the second particles are usually micrometer-order. Especially, mechanical properties were known to be enhanced largely. However, there is little report about how electroceramic properties are changed by making nanocomposite. Thus, in this research, we made PNN-PZT/Ag nanocomposite by hot-pressing method, and microscopic and dielectric properties are studied.