An experimental investigation on the structure and dynamic behavior of two dimensional over-expanded air jets exiting into water was carried out. The hish speed digital video imaging and static pressure distribution measurement were made to characterize the structure and time-dependant behavior of the jets. Mach number at the jet exit was 2.0 and was slightly less than the value predicted by the ideal nozzle calculation. Variance of jet spreading angle at different stagnation condition was measured as a function of mass flow rate. Periodic nature of the air jet distortion in water was observed and the frequency of the repetition was approximately 5-6 Hz for all cases tested. Three characteristic length scales were defined to characterize jet structure. $L_1$, maximum width of the plume when the periodic instability occurs, $L_2$, width of the jet where secondary reverse flow entrained jet flow and $L_3$, distance from the jet exit to the location where entrainment of the secondary reverse flow occurs. The ratio of $L_1$ and $L_2$ decreased with increasing stagnation pressure, i.e. mass flow rate. $L_3$ increased with increasing stagnation pressure. The temporal behavior of static pressure measurements also showed peak around frequency of 5, which corresponds the frequency obtained by visual measurements