NFPA-803 has been referred as the Fire Protection Standard at the Nuclear Power Plants of Pressurized Water Reactor. This Standard has been used as the fire protection regulation, containing prescriptive requirements with deterministic methodology. Recently, with cumulative efforts by the U.S. Nuclear Regulatory Commission and Utilities in America to establish a new Standard, including a quantitative evaluation methodology, NFPA-805, the Performance-Based Standard for FIRE Protection for Light Water Reactor Electric Generating Plants was issued and approved by the American National Standards Institute as an American National Standard with an effective date of February 9, 2001. This paper presents an analysis result from the computer modeling for the fire simulation In addition, it proposes the idea that this kind of analytic method can be available for the facilities design of fire prevention and protection fields, as well as an evaluation for the fire suppression system with a quantitative analysis for the thermal phenomena in fire compartments in Nuclear Power Plants.