The sequence of the propellant supply for ignition of a liquid rocket engine combustor is very important in the reliable and safe operation of the engine. The ignition sequence of KSR-III main engine was briefly described and the measuring parameters and their reliability determining ignition sequence were examined in this paper. The filling time of the engine propellant manifolds and the valve open/close time were reviewed to obtain the exact and reliable time of the propellant supply to the combustor. The combustion characteristics of the engine at starting were discussed at different supply lead of propellant. Finally, the hot firing test results with cyclogram determined by measuring parameters were presented.