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Self-Aggregation of Synthetic Magnesium Bacteriochlorins as a Photosynthetic Antenna Model
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  • Self-Aggregation of Synthetic Magnesium Bacteriochlorins as a Photosynthetic Antenna Model
  • Self-Aggregation of Synthetic Magnesium Bacteriochlorins as a Photosynthetic Antenna Model
저자명
Kunieda. Michio,Mizoguchi. Tadashi,Tamiaki. Hitoshi
간행물명
Journal of photoscience: an international journal officail organ of the Korean Society of Photoscience
권/호정보
2002년|9권 2호|pp.353-355 (3 pages)
발행정보
한국광과학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

We prepared 3-(1-hydroxyethyl)-bacteriopyrochlorophy11-a (3) possessing magnesium atom and phytyl ester from modification of natural bacteriochlorophyll(BChl)-a. A dichloromethane solution of (3$^1$R) and (3$^1$S)-3 was diluted with 100~1000 fold volume of cyclohexane to give new species absorbing near-infrared lights. The resulting Q, maximum of (3$^1$R)-3 was 860 nm and red-shifted by 2150 $cm^{-1}$ / from the monomeric. In the nonpolar organic solvent, epimeric (3$^1$S)-3 showed a 1ess red-shifted peak at 798 nm as well as a residual monomeric band. Such visible spectra indicated that 3 diastereose1ectively aggregated in cyclohexane to afford oligomers possessing a simi1ar supramolecular structure with chlorosomal aggregates of natural BChl-d, 7,8-dehydro-form of 3.