The mixing of propellant and its mass distribution of unlike-doublet impinging injector, which is known to affect the combustion efficiency significantly, have been studied using PLIF(Planar Laser Induced Fluorescence). The results show that fuel jet penetrates considerably into the oxidizer jet at impinging point as variation of momentum ratio. and then stream flows inclined because of variation of momentum ratio. Consequently, the mixing efficiency shows that maximum efficiency is at MR=3. after MR=3, mining efficiency decreases slightly.