In previous study, diesel-methanol stratified injection system is manufactured and applied to a D.I. diesel engine in order to realize combustion improvement using methanol, which is oxygenated fuel with large latent heat. We know that NOx and soot is reduced by stratified injection of diesel fuel-methanol. Therefore, in the present study, combustion diagnosis using optical measurement is tried to make clear effect of methanol on simultaneous reduction of NOx and soot. Two-color method is used to measure flame temperature and KL value, which is approximately proportional to the soot consentration along the optical path. Laser induced scattering method was used to measure distribution of soot at two dimensional area. Also, it is compared exhaust characteristics of NOx and soot with results of optical measurement.