This paper shows error in the polarization direction on ultrasonic transducers how sensitive the shear ultrasonic waves are to a little misoriented plies according to the angle variation of shear ultrasonic waves $0{circ},;45{circ}$ and $90{circ}$. Also, it is shown that shear waves, particularly the transmission mode with the transmitter and receiver perpendicular to cach other, have high sensitivity for detecting anomalies in fiber orientation and ply layup sequence that may occur in the manufacturing of composite laminates. Experimental results are agreed with a modeling solutions which was based on decomposition of shear wave polarization vector as it propagates through the composite laminates. This wave appeared considerably to be sensitive to CFRP composites to thickness direction along in-plane fibers.