In this study, the evaluation of environmental performance of the building energy system of domestic commercial sector was carried out. Based on the theory of linear programming model, we established an evaluation model satisfying object functions and constraint conditions. Employing the model, the evaluation of building energy system was performed under the consideration of cost and environmental constraint conditions. As an evaluation tool, MARKAL (MARKet Allocation) known as a market distribution model was employed. We analyzed scenarios of Case I (Base Scenarios) through Case IX established by the combination of the components of building energy system such as glazing, building skin, core, and heat source system. According to the results of the evaluation, highest contribution on the useful energy demand was obtained from the building energy system combined with solar heat source system, when the total amounts of $CO_2$ exhaust as an environmental constraint condition is assumed to be the level of 1995.