Second harmonic generation was measured in porous silicon superlattices surface which were made by changing and anodization current density and the anodization time periodically in the process of obtaining porous silicon. The technique of second harmonic generation is used as a probe to the surface of porous silicon superlattice by using Nd:YAG laser. We have investigated the surface structure and nonlinear-optics properties of porous silicon superlattice.