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The Effect of Induced Multipoles on the Fifth-order Raman Response
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  • The Effect of Induced Multipoles on the Fifth-order Raman Response
  • The Effect of Induced Multipoles on the Fifth-order Raman Response
저자명
Jansen. Thomas I.C.,Duppen. Koos,Snijders. Jaap G.
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2003년|24권 8호|pp.1102-1106 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

In our previous work we developed the Finite Field method in order to calculate the fifth-order Raman response. The method was applied to calculate various polarization components of the two-dimensional response of liquid $CS_2$. So far, all calculations relied on the dipole-induced dipole. Accurate time-dependent density functional theory calculations have shown that this model has big discrepancies, when molecules are close together as in the liquid. We now report results of investigations on the importance of multipole and electron overlap effects on the polarizability and the fifth-order Raman response. It is shown that these collision effects, especially the induced multipoles, are crucial in the description of the fifth-order response. The impact is found to be especially pronounced for the χ_{mmzzzz}^{(5)}$response that is solely due to interaction induced effects. The calculated response will be compared with various experimental results.