The pulse-echo method is one of the most widely used ultrasonic techniques for application of nondestructive evaluation. Particularly, quantitative nondestructive evaluation of defects has been considered more important to assure the reliability and the safety of structure. Frequency energy in adhesive joints is based on the ultrasonic wave analysis. The attenuation coefficient upon wave amplitude and the frequency energy that is expressed in the term of wave pressure amplitude were utilized for the primary wave experiment. By means of a control experiment, it was confirmed that the variation of the frequency energy in adhesive joints depends on transition by stress variation. In this paper, the ultrasonic characteristics were measured for single lap joint and Double Cantilever Beam specimen with different fracture modes that was subjected to stress. Consequently, the data that was obtained from the adhesive specimen was analytically compared to the fracture mechanics parameter