- 제주도 한라산 1100 고지 대기 에어로졸의 조성 및 특성
- ㆍ 저자명
- 김원형,강창희,신찬성,고선영,홍민선
- ㆍ 간행물명
- 한국대기환경학회지
- ㆍ 권/호정보
- 2003년|19권 2호|pp.145-156 (12 pages)
- ㆍ 발행정보
- 한국대기환경학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The atmospheric aerosols collected at the 1100 site located in Mt. Halla have been analyzed to investigate their compositions and chemical characteristics . The average concentrations of water-soluble cations were in the order of N $H_{4}$$^{+}$ > $Ca^{2+}$ > N $a^{+}$ > $K^{+}$ > $Mg^{2+}$ during the spring, showing high increase of $Ca^{2+}$ concentration with the value of 0.60 $mu extrm{g}$/ $m^3$, and N $H_{4}$$^{+}$> N $a^{+}$> $K^{+}$> $Ca^{2+}$ > $Mg^{2+}$ during the other seasons. The average concentrations of anions have shown in the order of S $O_{4}$$^{2-}$ > N $O_{3}$$^{[-10]}$ >C $l^{[-10]}$ for all seasons, and S $O_{4}$$^{2-}$ and N $O_{3}$$^{[-10]}$ had higher concentrations in spring with the values of 4.84 $mu extrm{g}$/ $m^3$ and 1.08 $mu extrm{g}$/ $m^3$, respectively. From the analytical data of size-segregated particles by cascade impactor sampling, the components of N $H_{4}$$^{+}$, S $O_{4}$$^{2-}$, N $O_{3}$$^{[-10]}$ and $K^{+}$ were distributed mainly in fine particles, but $Ca^{2+}$, N $a^{+}$, $Mg^{2+}$ and C $l^{[-10]}$ were included mostly in coarse particles. The correlation coefficients of nss-S $O_{4}$$^{2-}$/N $H_{4}$$^{+}$, nss-S $O_{4}$$^{2-}$/ $K^{+}$ and N $O_{3}$$^{[-10]}$ /nss-C $a^{2+}$ showed quite high values with 0.871, 0.857 and 0.654, respectively Based on the study of enrichment factors, it is considered that N $a^{+}$, $Mg^{2+}$, C $l^{[-10]}$ and $Ca^{2+}$ components were delivered from oceanic and soil sources, but S $O_{4}$$^{2-}$, N $O_{3}$$^{[-10]}$ and N $H_{4}$$^{+}$ might have other source origins. The factor analysis study showed the aerosol at the 1100 site was influenced mainly by anthropogenic factors, followed by oceanic and soil factors. followed by oceanic and soil factors.