The waveforms of partial discharges (PDs) imply physical and structural properties of PD sources, so analyzing them give us information on the kind of PD sources and the location. Waveforms of PD as a time series function have variable amplitudes but sustain a certain uniform shape, which shows well the characteristics of the waveforms and frequency region. They can also be used as parameters having time and frequency information of PD signals and applied to classification of multiple PDs sources via Artificial Neural Network with back propagation (BP) learning.