By blending of various low boiling point oxygenated agents to lower grade fuels, significant improvements were simultaneously obtained in smoke, CO, PM, SOF and BSEC. Especially, our trends were remarkably obtained by retarding injection timing, by decreasing boiling point and increasing blending contents of additives in case of oxygenated agents rather than non-oxygenated agents. Also, it was revealed that when 20vo1.% DMM added to high viscosity fuels and injection timing was retarded, NOx-smoke trade off relationship was much better than that of ordinary diesel fuel. Thus, lower grade fuels with high viscosity could be expected to be used efficiently and cleanly in diesel operation by blending low boiling point oxygenates.