Measurements on the combustion characteristics of dimethyl ether(DME:$CH_3$O$CH_3$) as compared with LPC in constant volume combustion chamber have been conducted. The DME is a good alternative fuel having oxygen component in fuel. To elucidate the combustion characteristics of dimethyl ether as a fuel, the combustion pressures, combustion durations, and pollutants(NOx, $CO_2$, CO) are measured with equivalence ratios(Ø), and initial Pressures of fuel-air mixture. In the case of DME, the NOx concentration peaks in leu flame Ø = 0.85~0.9, and $CO_2$ concentration peaks at Ø=1.1, while the CO concentration abruptly rises at the condition of fuel-rich mixtures.