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Chemical Modification of Isotactic Polypropylene by Melt Blending
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  • Chemical Modification of Isotactic Polypropylene by Melt Blending
  • Chemical Modification of Isotactic Polypropylene by Melt Blending
저자명
Kim. Jun-Young,Seo. Eun-Su,Park. Dae-Soon,Park. Kwang-Min,Kang. Seong-Wook,Lee. Chang-Hyung,Kim. Seong-Hum
간행물명
Fibers and polymers
권/호정보
2003년|4권 3호|pp.107-113 (7 pages)
발행정보
한국섬유공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The branched polypropylene (b-PP) was prepared by melt blending process with initiator, antioxidant, and functional monomers to improve the melt strength through the melt grafting. The melt flow index (MFI) of the b-PP was increased with increasing the initiator content. On the introduction of the alkylamine as the branching agents the MFI of the b-PP was increased, while that of the b-PP with the pentaerythritol triacrylate (PT) was decreased. It may be caused by the chain scission of the i-PP backbone due to the reduced thermal stability of the i-PP on the melt blending. The MFI of the b-PP without the antioxidant was increased due to the chain scission occurred during the melt processing, while on the introduction of the antioxidant, the MFI of the b-PP was decreased. The crystallization temperature of the b-PP was higher than that of PP, which was attributed to the branched chain structure. It was found that the PT was the most effective functional monomers for enhancing the melt properties of the b-PP.