A fast response NO analyzer was applied to investigate the relation between cycle-by-cycle NO emissions and combustion chamber pressure. NO emissions were sampled at an isolated exhaust manifold of 4-stroke spark ignition engine to avoid the interference of exhaust gas from other cylinders. The linear correlation analysis was performed with collected data of NO emissions and combustion chamber pressure with respect to the various air-fuel mixture ratios and engine loads. The sampled data sets were obtained during 200 cycles at each operating condition. The results showed that there was a typical pattern in NO emissions from an exhaust port through a cycle. It was possible to set a block of crank angle in which the linear correlation coefficient between NO emissions and combustion chamber pressure was high. As the engine load increased, NO emissions were more dependent on combustion chamber pressure after TDC. It was also analyzed that the correlation between two parameters with respect to air-fuel mixture ratio tended to increase as mixture went leaner. Furthermore, this correlation coefficient for the mixture near the lean limit seemed to be kept high even though combustion was unstable.