This paper examines a spatial pattern and processes of academic achievement in deprived area, considering relationship between academic achievement and social deprivation as social context. It links academic achievement data with neighborhood data from the 2001 UK Census(by ward) in South East England and uses multiple regression modeling to estimate the contribution of social deprivation to academic achievement of primary schools. The findings suggest that there is a significant positive relationship between deprivation in the local residential environment and academic achievement in primary schools. It also argues that more deprived area in South East England would tend to promote greater inequality of academic achievement in the spatial aspects, relating to Key Stage 2 score.