- ICP-MS를 이용한 알칼리암의 희토류원소 정량분석
- ㆍ 저자명
- 허순도,이종익,이미정,김예동,Hur. Soon-Do,Lee. Jong-Ik,Lee. Mi-Jung,Kim. Yea-Dong
- ㆍ 간행물명
- Ocean and polar research
- ㆍ 권/호정보
- 2003년|25권 1호|pp.53-62 (10 pages)
- ㆍ 발행정보
- 한국해양연구원
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Inductively coupled plasma mass spectrometry (ICP-MS) is useful instrument for determining abundance of rare earth elements, due to very low detection limits and rapid data acquisition. In this article, two methods are used for decomposition of alkaline rocks; close vessel acid digestion and $Na_2Co_3$ fusion. The two analytical results show good agreements. Considering total dissolved solids and detection limits, the most adequate dilution factor is 5,000 times. Polyatomic ion interferences during analysis can give rise to Inaccuracies. After correction from oxide and hydroxide interference, the analytical result show 20-30% decrease for Gd and Tm, 10-20% decrease for Tb and Er. In comparing the analytical results from KORDI with other institutes, most rare earth elements abundance show good agreements except Lu.