Boiler is one of the most important utilities providing steam to turbine in order to supply mechanical energy in thermal power plant. It is composed of thousands of tubes for high efficient heat transfer. Water is converted to steam inside the waterwall tubes. Many chemical components dissolved in boiler water come out of itself, deposit to the tube wall surface, prohibit heat transer, raise tube metal temperature, eventually fail the boiler tubes. Several tasks such as fracture surface study, tensile test, hardness test, metallurgical test, composition analysis of sticking elements were conducted to identify the root cause of tube failure.