In the production of internal combustion engines, there have been trends to develop the high performance engines with improved fuel efficiency, lighter weights and smaller sizes. This trends help to answer problems related to thermal load and abnormal combustion, etc. in these engines. In order to investigate these problems, a thin film-type probe and its manufacturing method for instantaneously measuring surface-temperatures have been proposed in this study, Instantaneous surface temperature of a constant volume combustion chamber was measured by this probe and heat flux was obtained by Fourier analysis. In order to thoroughly understand the characteristics of combustion, the authors measured the wall temperature of the combustion chamber and computed heat flux through a cylinder wall while varying the protrusion height of the probe have been measured. To achieve the above goals, a instantaneous temperature probe was developed, thereby making possible the analysis of the instantaneous temperature of wall surface and the detection of unsteady heat flux in the constant volume combustion chamber.