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Spontaneous Formation of Revival Waves in the 1,4-Cyclohexanedione-Bromate-Ferroin Reaction
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  • Spontaneous Formation of Revival Waves in the 1,4-Cyclohexanedione-Bromate-Ferroin Reaction
  • Spontaneous Formation of Revival Waves in the 1,4-Cyclohexanedione-Bromate-Ferroin Reaction
저자명
Huh. Do-Sung,Kim. Young-Joon,Kim. Hye-Sook,Kang. Jong-Kon,Choe. Sang-Joon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2004년|25권 2호|pp.267-270 (4 pages)
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대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

The bromate-1,4-cyclohexanedione-ferroin oscillating reactions are uncovered to support two types of wave activities, in which spontaneous formation of circular waves has been achieved after the disappearance of initial waves. The induction period of the revival wave is typically above 10 hours and its dependence on the initial concentrations of reactants is qualitatively different from that of initial waves. In addition to their differences in propagating speed and wavelength, the initial waves and the revival patterns have different colors, suggesting that different reaction mechanisms are involved in the formation of these spatiotemporal behaviors. Our experiments further show that the addition of hydroquinone to the reacting system can significantly shorten the induction time of the revival wave, which implicates that hydroquinone is not only a product in the bromate-1,4-cyclohexanedione-ferroin oscillating reaction but also plays a critical role in the following reactions.