기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
Crystal Structures and Magnetic Properties of Sparteinium Tetrahalocuprate Monohydrate Compounds
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • Crystal Structures and Magnetic Properties of Sparteinium Tetrahalocuprate Monohydrate Compounds
  • Crystal Structures and Magnetic Properties of Sparteinium Tetrahalocuprate Monohydrate Compounds
저자명
Lee. Yong-Min,Park. Sung-Min,Kang. Sung-Kwon,Kim. Young-Inn,Choi. Sung-Nak
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2004년|25권 6호|pp.823-828 (6 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

The crystal structures of sparteinium tetrachlorocuprate monohydrate $[(C_{15}H_{28}N_2)CuCl_4{cdot}H_2O]$, 1 and sparteinium tetrabromocuprate monohydrate $[(C_{15}H_{28}N_2)CBr_4{cdot}H_2O]$, 2, were determined. The structures of 1 [orthorhombic, $P2_12_12_1$, a = 8.3080(10) ${AA}$, b = 14.6797(19) ${AA}$ and c = 16.4731(17) ${AA}$], and 2 [orthorhombic, $P2_12_12_1$, a = 8.4769(7) ${AA}$, b = 15.166(3) ${AA}$ and c = 16.679(3) ${AA}$], are composed of a doubly protonated sparteinium cation, $[C_{15}H_{28}N_2]^{2+}$, a discrete $CuX_4^{2-}$ anion $(X=Cl^-;or;Br^-)$, and one water molecule. These monomeric compounds are stabilized through various types of hydrogen bonding interaction in their packing structures. Crystal 2 exhibits weak anti-ferromagnetism (J = -3.24 $cm^{-1}$) as opposed to the magnetically isolated paramagnetism observed for 1. The results of comparative magneto-structural investigations of 1 and 2 suggest that the pathway for the weak anti-ferromagnetic super-exchange in 2 might be through a Cu-Br${cdots}$Br-Cu contact.