The purpose of this study is to analyze the sales area of gas stations to see the quality and the efficiencies of spatial distribution structure for petroleum products in Tae-jeon City. Location pattern of gas station is classified by factors of competitive facilities, transportation, population and landuse in Tae-jeon City. As a result, High profit pattern and low profit pattern is classified. The characteristics of the distribution pattern of gas station are that the while densely populated has a small sales area, the thinly populated region has huge ones. Location-allocation model is used in order to minimize the travel distance from consumer location to gas station and balance the spatial distribution of gas station in case studies. The result reveals that the model-based locations of gas stations are more dispersed and balanced in the whole Tae-jeon City compared with the actual location of gas stations. This study shows the characteristics and spatial distribution patterns of sales area and location in petroleum products distribution facilities.