In the steel making industries, the continuous casting process has been applied to the number of company because of its economical benefit. Casting rolls are utilized for frictional drive and transport of solidifying slap. Dimensional tolerances, mechanical stability and surface condition of the cast roll can affect both the surface and internal quality of the product being cast. To overcome these problems, the industry is accelerating on the rate of technology improvements. Samples were overlaid on the S45C steel by submerged arc welding process. And the hardness, wear, electrochemical corrosion and oxidation tests were carried out. Test results were that all these materials were satisfying basic requirements of caster rolls. By these results, the addition of 0.1%Nb and 0.15%V increase mechanical properties and tempering resistance by its superior carbide forming characteristics in low carbon $12{sim}13%Cr$ martensitic stainless steels.