- 배당화 아크릴레이트와 메타크릴레이트의 효소적 합성
- Enzymatic Synthesis of Glycosyl Acrylate and Methacrylate
- ㆍ 저자명
- 박대원,김혜성,Park. Dae-Won,Kim. Hae-Sung
- ㆍ 간행물명
- 한국유화학회지
- ㆍ 권/호정보
- 2004년|21권 1호|pp.37-44 (8 pages)
- ㆍ 발행정보
- 한국유화학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Glycosyl acrylate and methacrylate were synthesized by lipase-catalyzed esterification of vinyl acrylate and vinyl methacrylate with ${eta}$-methyl glucoside in t-butanol as a reaction medium. At the optimum conditions of initial concentration of 150g/l ${eta}$-methyl glucoside, molar ratio of 1 : 3, 5%(w/v) lipase(Novozym 435) and $50^{circ}C$, we attained up to 100% conversion for enzymatic glycosylation of vinyl acrylate and vinyl methacrylate by supersaturated solvent process. The polymerizable glycosyl acrylates and methacrylate are expected to have biomedical application as hydrophilic monomers and hydration modifiers to be used for biocdmpatible hydrogel.