This research carried out ancient technique and composition of the relics recovered from the octagonal nine-storied pagoda of Woljeongsa temple using the scientific methods and obtained the following results. Firstly, The silver sarira inner case is consists of Ag, its materials comes out near 98wt%and comparing with the relics of Hwangnamdaechong, the contents of Ag and Ni are almost same with it. Secondly, The bronze sarira outer case, its contents of Cu is almost same with pure copper of which average is 99.7wt%. So, it should be named the copper sarira outer caserather than the bronze sarira outer case that has been called. Thirdly, The bronze mirror, though the contents of tin and lead are less than other contents which have been studied, they tend to have white color so they need to be made a close study. Especially, Because cultural property of nondestructive surface analytic method is not analyzed by the analysis of cross section and the moisten analysis, it may be occurred analytical errors by other factors.