- 유도용해법으로 제조된 Co1-xNbxSb3의 열전특성
- ㆍ 저자명
- 박종범,유신욱,조경원,장경욱,이정일,어순철,김일호,Park. J.B.,You. S.W.,Cho. K.W.,Jang. K.W.,Lee. J.I.,Ur. S.C.,Kim. I.H.
- ㆍ 간행물명
- 한국재료학회지
- ㆍ 권/호정보
- 2005년|15권 2호|pp.89-92 (4 pages)
- ㆍ 발행정보
- 한국재료학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The induction melting was employed to prepare Nb-doped $CoSb_3$ skutterudites and their thermoelectric properties were investigated. Single phase $delta-CoSb_3$ was successfully obtained by induction melting and subsequent annealing at $400^{circ}C$ for 2 hrs in vacuum. The positive signs of Seebeck coefficients for all the specimens revealed that Nb atoms acted as p-type dopants by substituting Co atoms. Electrical conductivity decreased and then increased with increasing temperature, indicating mixed conduction behavior. Electrical conductivity increased by Nb doping, and it was saturated at high temperature. Maximum value of the thermoelectric power factor was shifted to higher temperature with increasing the amount of Nb doping, mainly originated from the high Seebeck coefficient around mixed conduction temperature and high electrical conductivity.