Assembly of Six-Membered Vanadium Borophosphate Cluster Anions: Synthesis and Structures of (NH4)2(C2H10N2)6[BaH2O)5]2[V2P2BO12</S

Assembly of Six-Membered Vanadium Borophosphate Cluster Anions: Synthesis and Structures of (NH₄)₂(C₂H₁₀N₂)₆[BaH₂O)₅]₂[V₂P₂BO₁₂
Assembly of Six-Membered Vanadium Borophosphate Cluster Anions: Synthesis and Structures of (NH₄)₂(C₂H₁₀N₂)₆[BaH₂O)₅]₂[V₂P₂BO₁₂

ㆍ 저자명: Yun. Ho-Seop,Do. Jung-Hwan
ㆍ 간행물명: Bulletin of the Korean Chemical Society
ㆍ 권/호정보: 2005년|26권 1호|pp.146-150 (5 pages)
ㆍ 발행정보: 대한화학회
ㆍ 파일정보: 정기간행물|ENG|
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ㆍ 주제분야: 기타

이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.

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기타언어초록

Two new barium vanadium borophosphate compounds, $(NH_4)_2(C_2H_{10}N_2)_6[Ba(H_2O)_5]_2[V_2P_2BO_{12}]_6{cdot}8H_2O$, Ba- VBPO1 and $(NH_4)_8(C_3H_{12}N_2)_4[Ba(H_2O)_7][V_2P_2BO_{12}]_6{cdot}17H_2O$, Ba-VBPO2 have been synthesized by interdiffusion methods in the presence of diprotonated ethylenediamine and 1,3-diaminopropane. Compound Ba-VBPO1 has an infinite chain anion (${[BaH_2O)_5]_2[V_2P_2BO_{12}]_6}$$^{14-}$, whereas Ba-VBPO2 has a discrete cluster anion {[$Ba(H_2O)_7][V_2P_2BO_{12}]_6$}$^{16-}$. Crystal Data: $(NH_4)_2(C_2H_{10}N_2)_6[Ba(H_2O)_5]_2[V_2P_2BO_{12}]_6{cdot}8H_2O$, triclinic, space group P$overline{1}$ (no. 2), a = 13.7252(7) $AA$, b = 15.7548(8) $AA$, c = 15.8609(8) $AA$, α = 63.278(1)$^{circ}$, $eta$ = 75.707(1)$^{circ}$, $gamma$ = 65.881(1)$^{circ}$, Z = 1; $(NH_4)_8(C_3H_{12}N_2)_4[Ba(H_2O)_7][V_2P_2BO_{12}]_6{cdot}17H_2O$, monoclinic, space group C2/c (no. 15), a = 31.347(2) $AA$, b = 17.1221(9) $AA$, c = 22.3058(1) $AA$, $eta$ = 99.303(1)$^{circ}$, Z = 4.

키워드

Interdiffusion synthesis Assembly Crystal structure Vanadium borophosphates Cluster anion

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