기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
Lead-Selective Poly(vinyl chloride) Membrane Electrode Based on 1-Phenyl-2-(2-quinolyl)-1,2-dioxo-2-(4-bromo) phenylhydrazone
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • Lead-Selective Poly(vinyl chloride) Membrane Electrode Based on 1-Phenyl-2-(2-quinolyl)-1,2-dioxo-2-(4-bromo) phenylhydrazone
  • Lead-Selective Poly(vinyl chloride) Membrane Electrode Based on 1-Phenyl-2-(2-quinolyl)-1,2-dioxo-2-(4-bromo) phenylhydrazone
저자명
Zare. Hamid Reza,Ardakani. Mahammad Mazloum,Nasirizadeh. Navid,Safari. Javad
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2005년|26권 1호|pp.51-56 (6 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

A PVC membrane electrode for lead ion based on 1-phenyl-2-(2-quinolyl)-1,2-dioxo-2-(4-bromo) phenylhydrazone (PQDBP) as ionophore was demonstrated. The optimum composition of the membrane was 30 wt% poly(vinyl chloride), 60 wt% dibutyl phthalate as a plasticizer, 4 wt% ionophore and 6 wt% sodium tetraphenylborate as additive. The electrode exhibits a Nernstian response (28.7 mV decade$^{-1}$) for Pb$^{2+}$ over a wide concentration range (1.0 ${ imes}$ 10$^{-1}$ to 1 ${ imes}$ 10$^{-6}$ M) with a detection limit of 6.0 ${ imes}$ 10$^{-7}$ M. This sensor has a short response time and can be used for at least 2 months without any divergence in potentials. The proposed electrode could be used in a pH range of 3.0-6.0 and revealed good selectivities for Pb$^{+2}$ over a wide variety of other metal ions. It was successfully applied as an indicator electrode for the potentiometric titration of lead ion with potassium chromate and for the direct determination of lead in mine.