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Estimation of Ground and Excited State Dipole Moments of Coumarin 450 by Solvatochromic Shift Method
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  • Estimation of Ground and Excited State Dipole Moments of Coumarin 450 by Solvatochromic Shift Method
  • Estimation of Ground and Excited State Dipole Moments of Coumarin 450 by Solvatochromic Shift Method
저자명
Naik. L.R.,Math. N.N.
간행물명
Journal of photoscience: an international journal officail organ of the Korean Society of Photoscience
권/호정보
2005년|12권 2호|pp.57-61 (5 pages)
발행정보
한국광과학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The ground and excited state dipole moments of Coumarin 450 (C 450) laser dye were measured at room temperature in several solvents of varying dipole moments. The ground state dipole moment (${mu}_g$) is estimated by using the modified Onsagar model and the excited state dipole moments (${mu}_e$) were estimated by the method of solvatochromism as well as by utilizing the microscopic solvent polarity parameter ($E^N_T$). Further, the deviation of some of the points from the linearity of the $E^N_T$ versus Stokes shift indicates the existence of specific type of solute-solvent interaction. The excited state dipole moment of C 450 were found to be higher than those of the ground state and is interpreted in terms of the resonance structure of the molecule. A reasonable agreement has been observed between the values obtained by the method of solvatochromism and modified Onsagar model. It is observed that, corresponding to cyclohexane solution, the fluorescence maxima shift towards the red region with increasing the polarity of the solvents, hence the transition involved are of ${pi}-{pi}^*$ type.