Orientations of liquid crystal molecules on a surface of a film of photoreactive polyvinylcinnamate were investigated in order to apply as an alignment layer of LCD. When the polyvinylcinnamate film was exposed to linearly polarized W light, optical anisotropy was induced in the film through a selective photoreaction. Liquid crystal molecules on a surface of the film was aligned along the oriented polymer chain direction through intermolecular interactions. Thermal and light stability of the photoaligned LC cell were studied by investigating LC alignment changes after the alignment layer was treated with heat and W light. When the film was exposed with linearly polarized UV several times, the LC alignment was induced only along the final UV exposure direction.