In order to analyze the microscopic spray characteristics of free spray in ultra high pressure region, the droplets size and velocity of free spray injected under atmosphere condition were measured by PDPA. As injection pressure became ultra high pressure, the droplets size was decreased continuously due to the increase of mutual reaction between droplets and air. But the decreasing rate became moderate. The velocity was increased until 250 MPa, and then decreased over that of injection pressure. It was seemed that the droplet size was similar in range of $280~350;MPa$, but increased in 414 MPa, even though injection pressure was increased. The microscopic spray characteristics of free spray got worse in 414 MPa.