This study aims to identify grammatical relations (GRs) in Korean sentences. The key task is to find the GRs in sentences in terms of such GR categories as subject, object, and adverbial. To overcome this problem, we are fared with the many ambiguities. We propose a statistical model, which resolves the grammatical relational ambiguity first, and then finds correct noun phrases (NPs) arguments of given verb phrases (VP) by using the probabilities of the GRs given NPs and VPs in sentences. The proposed model uses the characteristics of the Korean language such as distance, no-crossing and case property. We attempt to estimate the probabilities of GR given an NP and a VP with Support Vector Machines (SVM) classifiers. Through an experiment with a tree and GR tagged corpus for training the model, we achieved an overall accuracy of $84.8\%,;94.1\%,;and;84.8\%$ in identifying subject, object, and adverbial relations in sentences, respectively.