This paper has dealt with the characteristics of mass and heat transfer of vertical flat plate with free convection. The theory of similarity transformations applied to the momentum and energy equations for free convection. To derive the similarity equation of mass transfer. the equation for conservation of species was added to the continuity. momentum and energy equations. The momentum, energy and species equations set numerically to obtain the velocity, temperature and mass fraction of species as dimensionless. For cases where momentum transport dominates, the thermal boundary layers are shorter than the momentum boundary layer. The relationships between momentum, energy and species were clarified from this study.