Support Vector Machines (SVM) is well known for a representative learner as one of the kernel methods. SVM which is based on the statistical learning theory shows good generalization performance and has been applied to various pattern recognition problems. However, SVM is basically to deal with a two-class classification problem, so we cannot solve directly a multi-class problem with a binary SVM. One-Per-Class (OPC) and All-Pairs have been applied to solve the face recognition problem, which is one of the multi-class problems, with SVM. The two methods above are ones of the output coding methods, a general approach for solving multi-class problem with multiple binary classifiers, which decomposes a complex multi-class problem into a set of binary problems and then reconstructs the outputs of binary classifiers for each binary problem. In this paper, we introduce the output coding methods as an approach for extending binary SVM to multi-class SVM and propose new output coding schemes based on the Error-Correcting Output Codes (ECOC) which is a dominant theoretical foundation of the output coding methods. From the experiment on the face recognition, we give empirical results on the properties of output coding methods including our proposed ones.