The purpose of this study is to improve the durability performance of polymer modified cement composites for repair of concrete under combined aging conditions. The experimental procedure was divided into three parts. First, the replacement level of mineral admixtures in polymer modified cement composites were determined in an experimental study based on a Box Behnken design. Second, the flow value, compressive strength and chloride permeability test of sixteen types of mixtures were conducted. Test results show that the polymer modified cement composites were effected on the improvement of the compressive strength and permeability performance. Third, the effects on the replacement level of silica fume mixture was evaluated by the compressive strength, chloride permeability, chemical resistance and repeated freezing and thawing cycles test. They demonstrated that the polymer modified cement composites using mixture of silica fume, fly ash, and blast furnace slag improved the durability performance.