In this paper, the performance of the WebService architecture for QoS guaranteed connection provisioning in inter-AS domain networks has been measured and analyzed for service publish/inquiry, collection of NMSs ASBR details, source routing by ingress NMS in constraint based routing and connection establishment. From the analysis, it has been found that, the connection between inter-AS domain networks can be established within the usual time limits of 3 seconds by the Web Service architecture. Since no standard solutions have been implemented in Interdomain QoS provisioning, this performance analysis assures Web Service architecture as a promising solution and can be easily implemented in the early stages of MPLS network employment.