- 메탄올을 환원제로 사용하는 과잉산소 분위기에서 $La_2O_3$ 촉매를 이용한 NO의 환원에 관한 연구
- ㆍ 저자명
- 김상환,유현주,박정규,Kim. Sang-Hwan,Yoo. Hyun-Ju,Park. Jung-Kyu
- ㆍ 간행물명
- 한국자동차공학회논문집
- ㆍ 권/호정보
- 2005년|13권 2호|pp.135-141 (7 pages)
- ㆍ 발행정보
- 한국자동차공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Nitric oxide(NO) reduction by methanol was investigated over $La_2O_3$ catalysts in the presence and absence of oxygen. In the absence of $O_2$, $CH_3OH$ reduced NO to both $N_2$ and $N_2O$, with selectivity to $N_2$ formation decreasing from 81-88% at 623K to 47-71% at 723 K. With 1.2% $O_2$ in the feed, the rates were 4-8 times higher, but the selectivity to $N_2$ dropped from 50% at 623 K to 9% at 723 K. The specific activities with $La_2O_3$ for this reaction were higher than those for other reductants; for example, at 773 K with hydrogen a specific activity of $34;{mu}mol;NO/sec{cdot}m^2$ was obtained whereas that for methanol was $638;{mu}mol;NO/sec{cdot}m^2$. The Arrhenius plots were linear under differential reaction conditions, and the apparant activation energy was consistantly near 15 kcal/mol with $CH_3OH$. Linear partial pressure dependencies based on a power rate law were obtained and showed a near-zero order in $CH_3OH$ and a near-first order in $H_2$.