The design process of a relational database system consists of requirement analysis, conceptual design using ER diagram, logical design, and physical design. In logical design process, the conceptual schema is transformed to relational schema, and relational schema is normalized. This traditional design process is hard to applied in real database design process, since there is an ambiguity in conceptual design process. In this paper, we suggest a new design process, which provides more structural design steps by removing the conceptual design process. In new approach, we produce the data flow diagram by the structural methodology. From the attributes in the data store of data flow diagram, we construct relational table schema, and we normalize relational schema. Finally we produced table relationship diagram in order to figure out relationships between tables.