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WC/Co 초경 스크랩 산화물의 고체탄소에 의한 환원/침탄
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저자명
이길근,하국현,Lee. Gil-Geun,Ha. Gook-Hyun
간행물명
한국분말야금학회지
권/호정보
2005년|12권 2호|pp.112-116 (5 pages)
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한국분말야금학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

In the present study, the focus is on the analysis of carbothermal reduction of oxide powder prepared from waste WC/Co hardmetal by solid carbon under a stream of argon for the recycling of the WC/Co hard-metal. The oxide powder was prepared by the combination of the oxidation and crushing processes using the waste $WC-8 wt.\%Co$ hardmetal as the raw material. This oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under a flowing argon atmosphere. The changes in the phase structure and gases discharge of the mixture during carbothermal reduction was analysed using XRD and gas analyzer. The oxide powder prepared from waste $WC-8wt.\%Co$ hardmetal has a mixture of $WO_{3} and CoWO_{4}$. This oxide powder reduced at about $850^{circ}C$, formed tungsten carbides at about $950^{circ}C$, and then fully transformed to a mixed state of tungsten carbide (WC) and cobalt at about $1100^{circ}C$ by solid carbon under a stream of argon. The WC/Co composite powder synthesized at $1000^{circ}C$ for 6 hours from oxide powder of waste $WC-8wt.\%Co$ hardmetal has an average particle size of $0.3 {mu}m$.