- 고밀도 플라즈마 화학 증착 장치를 이용한 $TiB_2$ 박막 제조
- ㆍ 저자명
- 이승훈,남경희,홍승찬,이정중,Lee. S. H.,Nam. K. H.,Hong. S. C.,Lee. J. J.
- ㆍ 간행물명
- 한국표면공학회지
- ㆍ 권/호정보
- 2005년|38권 2호|pp.60-64 (5 pages)
- ㆍ 발행정보
- 한국표면공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The ICP-CVD (inductively coupled plasma chemical vapor deposition) process was applied to the deposition of $TiB_2$ films. For plasma generation, 13.56 MHz r.f. power was supplied to 2-turn Cu coil placed inside chamber. And the gas mixture of $TiCl_4,;BCl_3,;H_2$ and Ar was used for $TiB_2$ deposition. $TiB_2$ films with high hardness (<40 GPa) were obtained at extremely low deposition temperature $(250^{circ}C)$, and the films hardness increased with ICP power and gas flow ratio of $TiCl_4/BCl_3$. The film structure was changed from (100) preferred orientation to random orientation with increasing RF power. It is supposed that the enhanced hardness of films was caused by a strong Ti-B chemical bonding of stoichiometric $TiB_2$ films and film densification induced by high density plasma.