The effects of change in injection pressure on spray structure in high temperature and pressure field have been investigated. The analysis of liquid and vapor phases of injected fuel is important for emissions control of diesel engines. Therefore, this work examines the evaporating spray structure using a constant volume vessel. The injection pressure is selected as the experimental parameter, is changed from 72MPa to 112MPa by using a common rail injection system(ECD-U2). The images of liquid and vapor phase in the evaporating free diesel spray are simultaneously taken by exciplex fluorescence method. As a result, it can be confirmed that the distribution of vapor concentration is more uniform in the case of the high injection than in that of the low injection pressure.